- Ep: 1
- Pilot
- Also Starring: Markus Redmond (Duane)
- And: Barbara Feldon (99)
- Guest Starring: Peter Crombie (Larz), Richard Riehle (Mr. Winters), Tony Longo (Agent 0 / Factory Worker), McNally Sagal (Agent 0 / Waitress), Jeff Nowinski (Agent 39)
- Written By: Michael J. DiGaetano & Lawrence Gay
- Directed By: Nick Marck
- Ep: 2
- Casino Evil
- Also Starring: Heather Morgan (Trudy)
- And: Barbara Feldon (99)
- Guest Starring: Terry Kiser (Carlo Monte), John Petlock (Ivan Buttinoff), J.J. Johnston (The Gambler)
- Featuring: Connie Sawyer (Agent 0 / Old Woman), Ryan Holihan (The Bellhop)
- Special Appearance By: Robert Goulet (Himself)
- Written By: Michael J. DiGaetano & Gary Apple
- Directed By: Nick Marck
- Ep: 3
- Goodbye Ms. Chip
- Also Starring: Heather Morgan (Trudy)
- And: Barbara Feldon (99)
- Guest Starring: Mark Roberts (The Brain), Dave Ketchum (Agent 13)
- Co-Starring: Tucker Smallwood (President Mazabuka), Greg Collins (The Marine)
- Featuring: Marcia Mitzman (The Kaos Chairwoman)
- Written By: Michael J. DiGaetano & Lawrence Gay
- Directed By: Nick Marck
- Ep: 4
- Shooting Up the Charts
- Guest Starring: Louis Mandylor (Georgio), Monty Hoffman (Eddie)
- Co-Starring: Alexander Enberg (Johnny Bloody), Phil LaMarr (The Jazz Singer)
- Written By: Gary Apple & Michael Carrington
- Directed By: Nick Marck
- Ep: 5
- Passenger 99
- Also Starring: Heather Morgan (Trudy)
- And: Barbara Feldon (99)
- Guest Starring: Kario Salem (The Turtle), Keone Young (Prime Minister Vanapopo)
- Co-Starring: Greg Travis (The Suspicious Man)
- Featuring: Marcia Mitzman (The Kaos Chairwoman), Gabrielle Boni (Agent 9), Jason Azikiwe (Carl the Control Controller), Tim Wrightman (The Pilot), Simone Gad (The Quirky Woman)
- Written By: Lawrence Gay & Michael J. DiGaetano
- Directed By: Nick Marck
- Ep: 6
- Wurst Enemies
- Also Starring: Heather Morgan (Trudy)
- Guest Starring: Bernie Kopell (Siegfried), Leah Lail (Jessica / Gretchen), Pat Millicano (Vince)
- Co-Starring: Phillip Simon (Phillipe)
- Featuring: Gabrielle Boni (Agent 9)
- Written By: Craig Hoffman
- Directed By: Nick Marck
- Ep: 7
- Liver Let Die
- Also Starring: Heather Morgan (Trudy)
- And: Barbara Feldon (99)
- Guest Starring: Richard Fancy (Dr. Mendelsohn), Lu Leonard (Nurse Scrum)
- Co-Starring: Steve Sheridan (Agent 24), Irwin Keyes (Agent 0 / Drowning Victim), Gail Boggs (Nurse #2)
- Featuring: Marcia Mitzman (The Kaos Chairwoman), Christopher Carrol (The Kaos Executive), Roger Nehls (The Patient)
- Written By: Lawrence Gay & Michael J. DiGaetano
- Directed By: Nick Marck
| Don Adams .................... Chief Maxwell Smart |
| Andy Dick .......................... Zachary Smart |
| Elaine Hendrix .......................... Agent 66 |
| Barbara Feldon .................. Congresswoman 99 |
| Heather Morgan ............................. Trudy |
