- Ep: 79
- Chuck Versus the Zoom
- Special Guest Star: Craig Kilborn (Roger Bale)
- And: Mark Hamill (Jean Claude)
- Guest Starring: Ethan Phillips (Woodley), Drew Slocum (Jim "Killer" Bernham)
- And: Richard Burgi (Clyde Decker)
- Co-Starring: Ben Cain (Stark)
- Written By: Chris Fedak & Nicholas Wootton
- Directed By: Robert Duncan McNeill
- Ep: 80
- Chuck Versus the Bearded Bandit
- Special Guest Star: Carrie-Anne Moss (Gertrude Verbanski)
- Guest Starring: Justin Hartley (Wesley Schenider)
- And: Jeff Fahey (Carl Schneider)
- Co-Starring: Katie Locke O'Brien (Groovy Lady), Joseph Ferrante (Gruff Guard), Charlet Chung (Susie Chin), David L. King (Executive)
- Written By: Rafe Judkins & Lauren LeFranc
- Directed By: Patrick Norris
- Ep: 81
- Chuck Versus the Frosted Tips
- Special Guest Star: Carrie-Anne Moss (Gertrude Verbanski)
- Guest Starring: Bonita Friedericy (General Diane Beckman), Mekenna Melvin (Alex McHugh)
- Co-Starring:
- Written By: Phil Klemmer
- Directed By: Paul Marks
- Ep: 82
- Chuck Versus the Business Trip
- Special Guest Star: David Koechner (Crazy Bob)
- Guest Starring: Bonita Friedericy (General Diane Beckman), Mekenna Melvin (Alex McHugh), Catherine Dent (Jane)
- And: Richard Burgi (Clyde Decker)
- Co-Starring:
- Written By: Kristin Newman
- Directed By: Allan Kroeker
- Ep: 83
- Chuck Versus the Hack Off
- Special Guest Star: Carrie-Anne Moss (Gertrude Verbanski)
- And: Beau Garrett (Cult Leader)
- Guest Starring: Eric Lange (Colin Davis), Freddie Wong (Freddie)
- With: Danny Pudi (Vali Chandrasekaren)
- And: Richard Burgi (Clyde Decker)
- Co-Starring: Jack Dimich (Timur), Derek Mears (Lance), Cesar Garcia (Shifty Inmate), Yvette Nicole Brown (Buy More Employee)
- Written By: Craig DiGregorio
- Directed By: Zachary Levi
- Ep: 84
- Chuck Versus the Curse
- Guest Starring: Bonita Friedericy (General Diane Beckman), Mekenna Melvin (Alex McHugh), Lee Reherman (Agent Simms)
- And: Rebecca Romijn (Robin Cunnings)
- Co-Starring: Alex Boling (Sommelier), Mikal Vega (Large Agent), Alex Marshall-Brown (Hostess), Joseph Gatt (Agent Hawk)
- Written By: Alex Katsnelson
- Directed By: Michael Schultz
- Ep: 85
- Chuck Versus the Santa Suit
- Special Guest Star: Brandon Routh (Daniel Shaw)
- Guest Starring: Bonita Friedericy (General Diane Beckman), Mekenna Melvin (Alex McHugh), Mo Collins (Colonel Caroline Hayne)
- And: Stan Lee (Himself)
- Co-Starring:
- Written By: Amanda Kate Shuman
- Directed By: Peter Lauer
- Ep: 86
- Chuck Versus the Baby
- Special Guest Star: Cheryl Ladd (Emma)
- Guest Starring: Tony Todd (CIA Director Graham), Mekenna Melvin (Alex McHugh)
- And: Tim DeKay (Kieran Ryker)
- Co-Starring:
- Written By: Rafe Judkins & Lauren LeFranc
- Directed By: Matt Barber
- Ep: 87
- Chuck Versus the Kept Man
- Special Guest Star: Carrie-Anne Moss (Gertrude Verbanski)
- Guest Starring: Omar Dorsey (St. Germaine), Mekenna Melvin (Alex McHugh), Marco Rodriguez (Rocky Falcone), Jim Tavare (Bald Bad Guy)
- Co-Starring:
- Written By: Craig DiGregorio & Phil Klemmer
- Directed By: Fred Toye
- Ep: 88
- Chuck Versus Bo
- Special Guest Star: Angus Macfadyen (Nicholas Quinn)
- Guest Starring: Mekenna Melvin (Alex McHugh), Ian Wolterstorff (Dale)
- And: Bo Derek (Herself)
- Co-Starring:
- Written By: Kristin Newman
- Directed By: Jeremiah Chechik
- Ep: 89
- Chuck Versus the Bullet Train
- Special Guest Star: Angus Macfadyen (Nicholas Quinn)
- Guest Starring: Mekenna Melvin (Alex McHugh), Erin Cahill (Bobbi)
- And: Ben Browder (Ron)
- Co-Starring:
- Written By: Nicholas Wootton
- Directed By: Buzz Feitshans IV
- Ep: 90
- Chuck Versus Sarah
- Special Guest Star: Angus Macfadyen (Nicholas Quinn)
- Guest Starring: Bonita Friedericy (General Diane Beckman)
- Written By: Rafe Judkins & Lauren LeFranc
- Directed By: Jay Chandrasekhar
- Ep: 91
- Chuck Versus the Goodbye
- Special Guest Star: Angus Macfadyen (Nicholas Quinn)
- And: Linda Hamilton (Mary Bartowski)
- Guest Starring: Bonita Friedericy (General Diane Beckman), Mekenna Melvin (Alex McHugh), Mark Pellegrino (Edgar), Vladimir Kulich (Renny)
- Co-Starring: Jessie Heiman (Fernando), Michael Kawczynski (Skip), Ilka Urbach (German Woman), Robert Duncan McNeill (Operative), Alexander Von Roon (Lutz), Lawrence Stachowiak (Larry), Daniel Samadani (Daniel), Gabrielle Eisenstadt (Gabbie), John Jurgens (John), Natasha Soudek (Wienerlicious Girl)
- Written By: Chris Fedak
- Directed By: Robert Duncan McNeill
| Zachary Levi ......... Charles Irving "Chuck" Bartowski |
| Yvonne Strahovski .............. Sarah Lisa Walker, CIA |
| Joshua Gomez ............................ Morgan Grimes |
| Ryan McPartlin ....... Devon "Captain Awesome" Woodcomb |
| Mark Christopher Lawrence ... Michael "Big Mike" Tucker |
| Scott Krinsky ............................. Jeff Barnes |
| Vik Sahay ................................ Lester Patel |
| Bonita Friedericy ............... General Diane Beckman |
| Sarah Lancaster ............. Eleanor "Ellie" Bartowski |
| Adam Baldwin .................... Major John Casey, NSA |
